The stress corrosion cracking scc of a commercial austenitic stainless steel type 304 was investigated as functions of chloride concentration, chromate concentration and test temperature under a. Corrosion under insulation cui is a severe problem for 304 stainless steel pressure vessel. The final, definitive version of this document can be found online at. Corrosion of astm 304 grade stainless steel for drinking. Chloride stress corrosion cracking inspectioneering. The combined action of tensile stress with corrosive environment can lead to chloride stress corrosion cracking cscc. Pdf chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in. Reference is often made to stainless steel in the singular sense as if it were one material. Next to water, chloride is the most common chemical found in nature. For example, lower service temperatures or reduced levels of chloride can substantially reduce the aggressiveness of the environment. Stress corrosion cracking of an austenitic stainless steel in nitritecontaining chloride solutions r. Three general classifications are used to identify stainless steels. Modes such as pitting, crevice, stress corrosion cracking, sulfide stress corrosion cracking, integranular, galvanic, contact, passivation and pickling are covered. Stress corrosion cracking of a 304 stainless steel elbow.
Methods of minimizing chloride stress corrosion cracking. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. Stress corrosion cracking of type 304 and type 316 austenitic stainless steels has been investigated as a function of chloride ion concentration in 0. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature. In most environments, the ppm are so small the effects on stainless are minute. For example, chloride stress corrosion cracking of austenitic stainless steel has been experienced in hotwater jacketed pipes carrying molten chocolate in the food industry. Scc is often associated with chlorides, but can also occur with caustics and other corrosive media.
Chlorideinduced stress corrosion cracking of 316 stainless steel oil tube hi everybody, today, i would like to show my case study to you. The effect of salt loading on chlorideinduced stress corrosion cracking in 304 l was studied at atmospheric pressure. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. This research was focused on the failure analysis of a cracked ss304 stainless steel elbow from a chemical plant.
The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of. Austenitic stainless steel may be susceptible to chloride stress corrosion cracking cscc. Stress corrosion cracking facts and how to reduce the risk. Localized corrosion and stress corrosion cracking of stainless steels. Stress corrosion cracking of an austenitic stainless steel. The failure cracks propagated from intergranular pickling damage to the 12inchthick steel, which was sensitized during initial fabrication. Transgranular stress corrosion cracking of 304l stainless. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. The roof was supported by stainless steel rods in tension, which failed due to stress corrosion cracking. Chloride stress corrosion cracking cscc is a type of intergranular corrosion. Chloride induced stress corrosion cracking of type 304. Intergranular stress corrosion cracking caused failure of two type 304 stainless steel outlet nozzles in highpurity heavywater moderator service in nuclear reactors. Corrosion of unprotected carbon steel occurs even inside reinforced.
Effects of laser peening on stress corrosion cracking scc of ansi 304 austenitic stainless steel author links open overlay panel j. Effects of laser peening on stress corrosion cracking scc. The standard 304 304l and 316316l grades are most susceptible. Stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Stress corrosion cracking of type aisi 304 stainless steel at room. Chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in air at a temperature of 353 k with relative humidity rh of. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries.
Mar 29, 2016 304 and its variant are general purpose stainless steel grade with good atmospheric corrosion resistance and many corrosive media. Corrosion resistance of stainless steels corrosion in concrete corrosion problems are not limited to outside surfaces. Chloride stress corrosion cracking and 316 stainless steel. Oct 21, 2019 chloride stress corrosion cracking cscc is a type of intergranular corrosion. Chloride stress corrosion involves selective attack of a metal along its grain boundaries. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic. Corrosion of stainless steel by hot caustic research using solutions of. Chlorideinduced stress corrosion cracking of 316 stainless. It is difficult to control the temperature, while changing pipe material or eliminating residual stresses associated with welding and forming the pipework is costly and. Mar 11, 2020 this research was focused on the failure analysis of a cracked ss304 stainless steel elbow from a chemical plant. Chloride stress corrosion cracking in austenitic stainless steel. This mode of attack is termed stress corrosion cracking scc.
Pitting and crevice corrosion can be avoided by either choosing a more corrosion resistant stainless steel or by changing the service environment so that it is less aggressive. The elbow was welded with two straight pipes at two ends. What forms of corrosion can occur in stainless steels. Singh raman 1, and wai hoong siew 2 1 department of mechanical and aerospace engineering, monash university, melbourne, victoria 3800, australia 2 mechanical engineer, ibm australia 60 city road melbourne, victoria 3006 australia. Pitting corrosion is avoided by making sure that stainless steel does not come into prolonged contact with harmful chemicals or by. Cracks were located mainly at positions close to the weld joint and the arc where very strong tensile residual stress existed. Chlorides are probably the single biggest enemy of stainless steel. In this study, a layer of adsorbed product film enriched in chromium and nickel was. The influence of chloride concentration and acidity on the occurrence of stress corrosion cracking s. Pdf chloride induced stress corrosion cracking of type 304. Chloride stress corrosion cracking and 316 stainless steel moltenmetal chemical 20 jul 11 07. Intergranular stress corrosion cracking caused failure of two type304 stainlesssteel outlet nozzles in highpurity heavywater moderator service in nuclear reactors. Kosaki 2008 evaluated performance of stainless steels, including 304, 304l, 316ln, and both base. Stress corrosion cracking of an austenitic stainless steel in.
While type 304 sensitized stainless steel suffer intergranular attack and scc in the. Tp304 ss and tp316 ss can occur when water containing chloride is present underneath insulation, external metal skin temperature exceeds approximately 50 c, and there is no surface protection or when the protective coating e. In 1985, 12 people were killed in uster, switzerland when the concrete roof of a swimming pool collapsed only after thirteen years of use. In this case, the most fashion of failure mode in ss is present. Summary of available data for estimating chlorideinduced scc. Pitting corrosion of stainless steels, on the other hand, occurs in solutions of all. The typical crack morphology for chloride stress corrosion cracking consists of branched transgranular cracks.
Stress relieved samples were uniaxially prestrained to 5% and were loaded with nine levels of mgcl 2, investigating cl. The effect of salt loading on chlorideinduced stress. The combination of tensile stress and a specific corrosive environment can crack stainless steels. Stress corrosion cracking in a brewery paul mueller company. Austenitic type 304 uns s30400 stainless steel is susceptible to stress corrosion cracking scc in acidic chloride cl. There is an additional risk of stress corrosion cracking scc at higher temperatures. Because austenitic stainless steels are prone to chlorideinduced stress corrosion cracking. Pdf chloride induced stress corrosion cracking of type 304 and. The stress corrosion cracking scc of a commercial austenitic stainless steel type 304 was investigated as functions of chloride concentration, chromate concentration and test temperature under a constant applied stress condition in 0.
Chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in air at a temperature of. Chloride stress corrosion cracking in austenitic stainless. The chloride ion cl is the most common of these and is found in everyday materials such as salt and bleach. The boundary of the cracking cone is shown aa a broken line. It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. There is an additional risk of stress corrosion cracking scc at. It subjects to pitting and crevice corrosion in warm chloride environments, and to stress corrosion cracking above about 60c.
Although no stainless steel grade is totally immune. While fluoride is more abundant than chloride in crustal rocks, fluoride is. In this study, a layer of adsorbed product film enriched in chromium and nickel was found to form on the metal surface in the solutions. The most common environmental exposure condition responsible for scc of stainless steels is the presence of chlorides. Pitting or crevice corrosion can occur on most stainless steel grades. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of this discussion. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. Pitting corrosion the passive layer on stainless steel can be attacked by certain chemical species. The effect of chloride ions on stress corrosion cracking of type 304. Stress corrosion cracking scc is a common issue with many specialty alloys.
As its name suggests, scc takes the form of a network of cracks that eventually will lead to sudden, catastrophic failure in your tanks. Austenitic stainless steels chloride induced stress corrosion cracking cscc chumpes petroleum 16 mar 18 10. Stress corrosion cracking of austenitic type 304 stainless. Chloride stress corrosion cracking clscc is one of the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Stress corrosion cracking of type 304 austenitic stainless. Analysis of initiation and propagation of stress corrosion. External chloride stress corrosion cracking ecscc of insulated austenitic stainless steels e. Chloride induced stress corrosion cracking of 316 stainless steel oil tube hi everybody, today, i would like to show my case study to you. Austenitic steels of type astm 304 and 316 austenitic steels have limited.
Scc is a form of corrosion that occurs in nearly all alloys, including the grades of stainless steel commonly used in brewery equipment types 304, 304l, 316, and 316l. Pitting corrosion has been reported from household bleach spills on stainless steel 304 type sinks in domestic environments. Increasing nickel content above 18 to 20% or the use of duplex, or ferritic stainless steels improves resistance to cscc. Figure 1 shows the cracking that occurred on a 6mo super austenitic stainless steel n08367 exposed to 0. Stainless steel provides both strength and corrosion resistance inside the concrete, providing a long, maintenancefree service life of the structure. Stress corrosion also called stress corrosion cracking or chloride stress corrosion. Super duplex and super austenitic stainless steels are considered virtually immune to chloride stress cracking. This study is to identify factors responsible for loss of production due to problems in plant and equipment. A precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. Stress corrosion cracking of sensitized type 304 stainless. Austenitic stainless steels chloride induced stress.
The observed crack propaga tion is the result of the combined and synergistic interaction of mechanical stress and corrosion re actions. Jan 08, 2002 while stainless steels are often used for their corrosion resistance, they do in fact suffer from corrosion under certain circumstances. Stress corrosion cracking susceptibility of 304l substrate and. Ammonium hydroxide stainless steela ahow good resistance to all concentrations of ammonia. A atreaa corrosion cracking zone baaed on faihrea reported in the literature is also shown in the graph.
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